巯基改性凹凸棒石黏土对土壤有效态镉及油菜吸收镉的影响     

付成  雷泞菲  裴向军  李军亚  徐欢  苏鑫  朱霞萍 《岩石矿物学杂志》2022,41(5):941-949

重金属不可降解,长期存在于土壤环境会严重影响作物安全。添加巯基改性凹凸棒石黏土(ATP-SH)到不同Cd污染程度土壤中,进行盆栽油菜实验,以石墨炉原子吸收光谱法测定了土壤有效态Cd和油菜不同部位Cd的含量;采用SPSS讨论了ATP-SH添加量、土壤有效态Cd、油菜不同部位Cd的相关性;计算了油菜对Cd的富集系数及转运系数,探究了ATP-SH对土壤Cd的钝化效果及对油菜富集和转运Cd的影响。实验结果显示,添加ATP-SH后,土壤有效态Cd、油菜各部位Cd含量显著降低,土壤有效态Cd降低率为40.65%~74.27%,油菜根、茎、枝、菜籽中Cd降低率分别为29.36%~79.46%、41.44%~88.45%、43.19%~95.89%和38.02%~95.81%;ATP-SH添加量与土壤有效态Cd、油菜各部位Cd含量均呈显著或极显著负相关,土壤有效态Cd与油菜各部位Cd含量均呈显著或极显著正相关,油菜各部位之间的Cd含量存在明显正相关关系;对照组油菜根、茎、枝、菜籽对Cd的富集系数分别是实验组的1.42~4.87倍、1.71~8.66倍、1.92~24.43倍、1.61~23.76倍,油菜各部位Cd的转运系数的大小是茎＞枝＞菜籽,且茎远大于枝和菜籽,是枝和菜籽转运系数的3.5~25倍。综上,ATP-SH能降低土壤Cd的生物有效性,阻隔土壤Cd向油菜迁移。  相似文献   

基于Hoek-Brown的岩石横观各向同性屈服准则研究     

郑艳妮  张强  张升  贾朝军  雷明锋 《岩土力学》2022,(1):139-151

为了描述岩石强度的各向异性特征,通过引入材料的微结构张量,考虑单轴抗压强度σ_cβ随层理倾角β而变化,提出了基于微结构张量的修正Hoek-Brown屈服准则。开展不同层理倾角(0°、15°、30°、45°、60°、75°和90°)的页岩试样不同围压(0、5、10、15和20 MPa)下的三轴压缩试验,结果显示,页岩峰值强度与层理倾角β呈"U"形曲线关系,在围压较低时呈"肩"形曲线关系,弹性模量E_t和泊松比ν对围压不敏感,其平均值随层理倾角β的变化关系分别呈倒"U"形、"肩"形。页岩的微观和宏观破坏图像表明,其破坏模式受围压和层理倾角双重控制。试验值与模型预测值的对比表明,修正的Hoek-Brown屈服准则可较好地对页岩强度的各向异性进行模拟。同时,采用Koteshwar千枚岩、Koteshwar板岩、绿泥石片岩等层状结构岩石的单轴和三轴压缩试验数据,进一步验证了提出的修正Hoek-Brown屈服准则对多数具有层理结构的横观各向同性岩石峰值强度模拟具有普遍适用性,并对屈服准则在试验数据较多和较少情况下的峰值强度模拟效果进行了评价。  相似文献   

含气软黏土的不排水抗剪强度计算模型     

郑威威  洪义  王立忠 《岩土力学》2022,43(8):2233-2240

含气软黏土广泛分布在世界五大洲,大量离散气泡的存在对软黏土的不排水抗剪强度具有强化或损伤作用,然而目前仍缺乏能综合考虑气相强化与气相损伤竞争机制的含气土不排水剪切强度解析表达式。结合临界状态土力学理论,基于笔者提出的含气土屈服函数,建立了v-lnp¢ 空间下临界状态线截距与土体含气特性(u_{w 0},y₀)的数学关系,进而推导了含气软黏土在三轴应力状态下不排水抗剪强度s_u的理论显式表达式。同时,采用所提出的含气软黏土不排水抗剪强度理论计算公式,分别对比了3种典型的含气软黏土在不同含气特性下的不排水抗剪强度理论预测与试验结果,包括马来西亚高岭土、Combwich 黏土和高岭黏土。另外,对比分析了4种不同的含气软黏土不排水抗剪强度理论计算模型的预测误差百分比,证明了提出的基于改进的含气软黏土本构模型的不排水抗剪强度理论计算式的合理性,能够更加准确地同时考虑含气软黏土的气相强化与气相损伤双重效应。  相似文献   

1991—2015年三江源河曲高寒草甸干湿状况及牧草产量变化的气候归因研究     

罗谨  王军邦  杨永胜  张光茹  祝景彬  贺慧丹  李英年 《冰川冻土》2021,43(5):1542-1550

以三江源东部河曲高寒草甸为研究对象,通过分析1991—2015年气温、降水、潜在蒸散、湿润指数和牧草产量变化特征,探讨了地区干湿状况对牧草产量的影响。研究表明：1991—2015年河曲高寒草甸潜在蒸散以3.5 mm·a^-1的速率增加（P<0.01）,在年降水量按2.3 mm·a^-1呈非显著性（P>0.05）增加的趋势下,地区干湿状况基本保持平稳（多年均值为0.52）,隶属于半湿润气候区。25年来牧草干重产量平均为303.7 g·m^-2,并以3.0 g·m^-2·a^-1的速率下降。分析牧草产量与影响干湿状况的气候因素之间的相关性发现,气温对牧草产量影响不明显（P>0.05）,降水量表现为正相关关系（P>0.10）,说明该区域降水是牧草产量提高与否的主导因素;牧草产量与潜在蒸散表现为负相关关系（P>0.10）,与湿润指数表现为正相关关系（P>0.10）;在生长季时期,牧草产量与降水量、潜在蒸散和湿润指数的相关性关系达到了显著水平（P<0.10）,说明牧草产量在生长季对地区环境条件湿润与否较为敏感。  相似文献   

成层软土地基预固结处理后桩基水平承载力估算方法     

黄朝煊  袁文喜  胡国杰 《岩土力学》2021,(1):113-124,134

目前通过对软土地基预加固处理来提高桩基水平承载力已被工程界认可,但如何在工程前期设计过程中估算软土地基预处理后桩基水平承载力提高值仍是技术难点。基于此,参考Bowles[1]的地基土水平抗力计算式,同时考虑成层软土地基预排水固结处理影响,通过数学推导,推求出根据原状软土室内土工试验抗剪强度指标及预加固处理时间,估算软土地基预处理后桩基水平承载力提高值的实用计算方法。考虑桩侧土弹塑性屈服影响,推导出成层软土中水平受荷桩弹塑性解析解及塑性区深度的计算式,给出了桩顶水平位移、桩身最大弯矩的无量纲计算式及相关计算源代码。依托于浙江省某水闸桩基工程案例,根据提出的计算方法对桩基水平承载力、桩顶水平位移及桩身最大弯矩等性状进行预估计算,并与地基预处理前、后现场试桩检测值进行验证对比,认为桩基水平承载力、桩顶水平位移及桩身最大弯矩等预估计算成果与工程现场试桩的检测值较接近,对类似工程设计具有较好的参考价值。  相似文献   

九龙江口浮游植物群体对盐度胁迫的快速适应     

李刚 《海洋学报(英文版)》2019,38(8):78-85

Mixing of freshwater and seawater creates the well-known salinity gradients along the estuaries. In order to investigate how phytoplankton respond to the acute salinity changes, we exposed natural phytoplankton assemblies from the Jiulong River Estuary to differential saline field water while continuously monitoring their photosynthetic performances under both indoor-and outdoor-growth conditions. When the natural cell assemblies from salinity 30 field water were exposed to series low saline field water(salinity 25, 17, 13 and 7.5), the effective Photosystem II quantum yield(ΔF/F_m′) decreased sharply, e.g., to one-fifth of its initials after 5 min exposure to salinity 7.5 field water, and then increased fast during the following 40 min and almost completely recovered after 320 min. During such an exposure process, non-photochemical quenching(NPQ) sharply increased from 0 to 0.85 within 5 min, and then decreased to nearly 0 within the following 70 min. When these cells re-acclimated to salinity 7.5 field water were exposed to series high saline field water(salinity 13, 17, 25 and 30), a similar response pattern was observed, with the decreased ΔF/F_m′ accompanied with increased NPQ, and followed by the recovery-induced increase in ΔF/F_m′ and decrease in NPQ. A similar response pattern as ΔF/F_m′to the acute osmotic stress was also observed in the photosynthetic carbon fixation capacity according to radiocarbon(~(14)C) incorporation. Our results indicate that estuarine phytoplankton assemblies could rapidly recover from the acute osmotic stress, implying a potential cause for their frequent blooms in coastal-estuarine waters where despite drastically varying salinity, available nutrients are abundant due to the land-derived runoffs or mixing-caused relaxations from sediments.  相似文献   

考虑劣化屈服老化裂纹后混凝土水库堤坝排水边坡抗震性研究          下载免费PDF全文

石晶  李伟 《地震工程学报》2019,41(6):1506-1513

针对在水库堤坝排水边坡混凝土裂纹的抗震性研究中,未考虑岩土体抗剪强度参数的劣化屈服效应以及混凝土裂纹的老化,存在抗震性判断结果准确率较差等问题,提出水库堤坝排水边坡混凝土考虑老化后产生裂纹的抗震性能研究方法。模拟强震下边坡混凝土的开裂破坏过程,根据D-P屈服准则,实现对闸墩混凝土材料的屈服判断。采用薄层整体单元模拟和分离式裂纹单元,实现混凝土裂纹的数值模拟,加载地震波后,获取混凝土裂纹的强震响应规律与破坏特征。实验结果可知,本文方法对坝体位移变化的研究精度高,得到的混凝土裂纹扩展范围更为准。运用本文方法对水库堤坝排水边坡混凝土的抗震性研究准确率以及可信度较高,说明本文方法具有一定的可取性。  相似文献   

Effects of different spatial distributions of physical soil crusts on runoff and erosion on the Loess Plateau in China   总被引：1，自引：0，他引：1       下载免费PDF全文

Pei Lu  Xinli Xie  Linhua Wang  Faqi Wu 《地球表面变化过程与地形》2017,42(13):2082-2089

The response of runoff and erosion to soil crusts has been extensively investigated in recent decades. However, there have been few attempts to look at the effects of spatial configuration of different soil crusts on erosion processes. Here we investigated the effects of different spatial distributions of physical soil crusts on runoff and erosion in the semi‐arid Loess Plateau region. Soil boxes (1.5 m long × 0.2 m wide) were set to a slope of 17.6% (10°) and simulated rainfall of 120 mm h^?1 (60 minutes). The runoff generation and erosion rates were determined for three crust area ratios (depositional crust for 20%, 33%, and 50% of the total slope) and five spatial distribution patterns (depositional crust on the lower, lower‐middle, middle, mid‐upper, and upper slope) of soil crusts. The reduction in sediment loss (‘sediment reduction’) was calculated to evaluate the effects of different spatial distributions of soil crusts on erosion. Sediment yield was influenced by the area ratio and spatial position of different soil crusts. The runoff rate reached a steady state after an initial trend of unsteadily increasing with increasing rainfall duration. Sediment yield was controlled by detachment limitation and then transport limitation under rainfall. The shifting time of erosion from a transport to detachment‐limiting regime decreased with increasing area of depositional crust. No significant differences were observed in the total runoff among treatments, while the total sediment yield varied under different spatial distributions. At the same area ratio, total sediment yield was the largest when the depositional crust was on the upper slope, and it was smallest when the crust was deposited on the lower slope. The sediment reduction of structural crust (42.5–66.5%) was greater than that of depositional crust (16.7–34.3%). These results provide a mechanistic understanding of how different spatial distributions of soil crusts affect runoff and sediment production. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Changes to sediment sources following wildfire in a forested upland catchment,southeastern Australia     

Hugh G. Smith  Gary J. Sheridan  Patrick N. J. Lane  Philip J. Noske  Henk Heijnis 《水文研究》2011,25(18):2878-2889

Few investigations link post‐fire changes to sediment sources and erosion processes with sediment yield response at the catchment scale. This linkage is essential if downstream impacts on sediment transport after fire are to be understood in the context of fire effects across different forest environments. In this study, we quantify changing source contributions to fine sediment (<63 µm) exported from a eucalypt forest catchment (136 ha) burnt by wildfire. The study catchment is one of a pair of research catchments located in the East Kiewa River valley in southeastern Australia that have been the subject of a research program investigating wildfire effects on runoff, erosion, and catchment sediment/nutrient exports. This previous research provided the opportunity to couple insights gained from a range of measurement techniques with the application of fallout radionuclides ¹³⁷Cs and ²¹⁰Pb_ex to trace sediment sources. It was found that hillslope surface erosion dominated exports throughout the 3·5‐year post‐fire measurement period. During this time there was a pronounced decline in the proportional surface contribution from close to 100% in the first six months to 58% in the fourth year after fire. Over the study period, hillslope surface sources accounted for 93% of the fine sediment yield from the burnt catchment. The largest decline in the hillslope contribution occurred between the first and second years after fire, which corresponded with the previously reported large decline in sediment yield, breakdown of water repellency in burnt soils, substantial reduction in hillslope erodibility, and rapid surface vegetation recovery. Coupling the information on sediment sources with hillslope process measurements indicated that only a small proportion of slopes contributed sediment to the catchment outlet, with material derived from near‐channel areas dominating the post‐fire catchment sediment yield response. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Rainstorm-generated sediment yield model based on soil moisture proxies (SMP)     

Sushindra Kumar Gupta  Pushpendra K. Singh  Jaivir Tyagi  Gunwant Sharma  Ajay Singh Jethoo 《水文研究》2020,34(16):3448-3463

This study develops improved Soil Moisture Proxies (SMP) based suspended sediment yield (SMPSY) models corresponding to three antecedent moisture conditions (AMCs) (i.e., AMC-I-AMC-III) by coupling the improved initial abstraction (I_a-λ) model, the SMA procedure and the SMP concept for modelling the rainfall generated suspended sediment yield. The SMPSY models specifically incorporate a watershed storage index (S) model to accentuate the transformation from storm to storm and to avoid the sudden jumps in sediment yield computation. The workability of the SMPSY models is tested using a large dataset of rainfall and sediment yield (98 storm events) from twelve small watersheds and a comparison has been made with the existing MSY model. The goodness-of-fit (GOF) statistics is evaluated in terms of the Nash Sutcliffe efficiency (NSE), and error indices, i.e., root mean square error (RMSE), normalized root mean square error (nRMSE), standard error (SE), mean absolute error (MAE), and RMSE-observations standard deviation ratio (RSR). The NSE values vary from 74.31% to 96.57% and from 75.21% to 91.78%, respectively for the SPMSY and MSY model. The NSE statistics indicate that the SMPSY model has lower uncertainty in simulating sediment yield as compared to the MSY model. The error indices are lower for the SMPSY model than the MSY model for most of the watersheds. These results show that the SMPSY model has less uncertainty and performs better than the MSY model. A sensitivity analysis of the SMPSY model shows that the parameter β is most sensitive followed by parameter S, α and A. Overall, the results show that the characterization of soil moisture variability in terms of SMPs and incorporation of improved delivery ratio and runoff coefficient relationship improves the simulation of the erosion and sediment yield generation process.  相似文献